Hi and welcome to the forum.
There is so much to do you will not we bored!!! For booking activities you should wait till you arrive, it will be lots cheaper. There are tour desks everywhere on the streets, literally.
For heaps of ideas check out Cathy and garys travel pages, there is more info here than you will ever need.
http://www.cathyandgarystravelpages.com/phuket.htm My top pick of things to do are.
Phuket Sail tour
Quad Bikes
Fantasea
Michelle